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Title: Supramolecular surface-confined architectures created by self-assembly of triangular phenylene-ethynylene macrocycles via van der Waals interaction
Authors: Tahara, Kazukuni ×
Lei, Shengbin
Adisoejoso, Jinne
De Feyter, Steven
Tobe, Yoshito #
Issue Date: 2010
Publisher: Royal Society of Chemistry
Series Title: Chemical Communications vol:46 issue:45 pages:8507-8525
Abstract: At the liquid/graphite interface triangular and rhombic phenylene-ethynylene macrocycles substituted by alkyl chains self-assemble to form porous two-dimensional (2D) molecular networks of honeycomb and Kagome types, respectively, or close-packed non-porous structures via alkyl chain interdigitation as the directional intermolecular linkages. Factors that affect the formation of the 2D molecular networks, such as alkyl chain length, solvent, solute concentration, and co-adsorption of guest molecules, were elucidated through a systematic study. For the porous networks, various molecules and molecular clusters were adsorbed in the pores reflecting the size and shape complementarity, exploring a new field of 2D host-guest chemistry.
ISSN: 1359-7345
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
× corresponding author
# (joint) last author

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