Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid-solid interface
Elemans, Johannes A. A. W × Wezenberg, Sander J Coenen, Michiel J. J Escudero-Adan, Eduardo C Benet-Buchholz, Jordi den Boer, Duncan Speller, Sylvia Kleij, Arjan W De Feyter, Steven #
Royal Society of Chemistry
Chemical Communications vol:46 issue:15 pages:2548-2550
Nickel salophens exclusively form monolayers at a liquid-solid interface, while in contrast zinc salophens mainly self-assemble into bilayers via axial ligand self-coordination which can be disrupted by the addition of pyridine axial ligands.