Title: Titanosilicate Beads with Hierarchical Porosity: Synthesis and Application as Epoxidation Catalysts
Authors: Lin, K
Lebedev, O
Van Tendeloo, G
Jacobs, Pierre
Pescarmona, Paolo # ×
Issue Date: 2010
Publisher: VCH Verlagsgesellschaft
Series Title: Chemistry - a European Journal vol:16 issue:45 pages:13509-13518
Abstract: Porous titanosilicate beads with a diameter of 0.5–1.5 mm (TiSil-HPB-60) were synthesized from a preformed titanosilicate solution with a porous anion-exchange resin as template. The bead format of this material enables its straightforward separation from the reaction mixture in its application as a liquid-phase heterogeneous catalyst. The material displays hierarchical porosity (micro/mesopores)
and incipient TS-1 structure building units. The titanium species are predominantly located in tetrahedral framework
positions. TiSil-HPB-60 is a highly active catalyst for the epoxidation of cyclohexene with t-butyl hydroperoxide
(TBHP) and aqueous H2O2. With both oxidants, TiSil-HPB-60 gave higher epoxide yields than Ti-MCM-41 and TS-1. The improved catalytic performance of TiSil-HPB-60 is mainly ascribed to the large mesopores favoring the diffusion of reagents and products to and from the titanium active sites.
The epoxide yield and selectivity could be further improved by silylation of the titanosilicate beads. Importantly, TiSil-HPB-60 is a stable catalyst immune to titanium leaching, and can be easily recovered and reused in successive catalytic cycles without significant loss of
activity. Moreover, TiSil-HPB-60 is active and selective in the epoxidation of a wide range of bulky alkenes.
ISSN: 0947-6539
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

Files in This Item:

There are no files associated with this item.

Request a copy


All items in Lirias are protected by copyright, with all rights reserved.

© Web of science