Title: Immobilization of molecular catalysts in supported ionic liquid phases
Authors: Van Doorslaer, Charlie ×
Wahlen, Joos
Mertens, Pascal
Binnemans, Koen
De Vos, Dirk #
Issue Date: 2010
Publisher: Royal Society of Chemistry
Series Title: Dalton Transactions vol:39 issue:36 pages:8377-8390
Abstract: In a supported ionic liquid phase (SILP) catalyst system, an ionic liquid (IL) film is immobilized on a high-surface area porous solid and a homogeneous catalyst is dissolved in this supported IL layer, thereby combining the attractive features of homogeneous catalysts with the benefits of heterogeneous catalysts. In this review reliable strategies for the immobilization of molecular catalysts in SILPs are surveyed. In the first part, general aspects concerning the application of SILP catalysts are presented, focusing on the type of catalyst, support, ionic liquid and reaction conditions. Secondly, organic reactions in which SILP technology is applied to improve the performance of homogeneous transition-metal catalysts are presented: hydroformylation, metathesis reactions, carbonylation, hydrogenation, hydroamination, coupling reactions and asymmetric reactions.
ISSN: 1477-9226
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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