Title: The use of ultrastable Y zeolites in the Ferrier rearrangement of acetylated and benzylated glycals
Authors: Levecque, Pieter ×
Gammon, David W
Jacobs, Pierre
De Vos, Dirk
Sels, Bert #
Issue Date: 2010
Publisher: Royal soc chemistry
Series Title: Green chemistry vol:12 issue:5 pages:828-835
Abstract: The Ferrier rearrangement of a selection of protected glycals was successfully performed using a commercially available H-USY zeolite CBV-720 as catalyst, selected after screening a range of similar catalysts. By incorporating either alcohols, thiophenol, trimethylsilyl azide or allyltrimethylsilane in the reaction it was shown that a range of O-, S-, N- and C-glycosides could be formed. With benzylated glucal and galactal in particular, use of the CBV-720 catalyst led to significantly higher yields of the 2,3-dehydroglycosides than previously reported.
ISSN: 1463-9262
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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