Title: Cobalt(II) complexes of nitrile-functionalized ionic liquids
Authors: Nockemann, Peter ×
Pellens, Michael
Van Hecke, Kristof
Van Meervelt, Luc
Wouters, Johan
Thijs, Ben
Vanecht, Evert
Parac-Vogt, Tatjana
Mehdi, Hasan
Schaltin, Stijn
Fransaer, Jan
Zahn, Stefan
Kirchner, Barbara
Binnemans, Koen #
Issue Date: 2010
Publisher: VCH Verlagsgesellschaft
Series Title: Chemistry - a European Journal vol:16 issue:6 pages:1849-1858
Abstract: A series of nitrile-functionalized ionic liquids were found to exhibit temperature-dependent miscibility (thermomorphism) with the lower alcohols. Their coordinating abilities toward cobalt(II) ions were investigated through the dissolution process of cobalt(II) bis(trinfluoromethylsulfonyl)-imide and were found to depend on the donor abilities of the nitrile group. The crystal structures of the cobalt(II) solvates [Co(C(1)C(1CN)Pyr)(2)(Tf2N)(4)] and [Co(C(1)C(2CN)Pyr)(6)][Tf2N](s). which were isolated from ionic-liquid solutions. gave in insight into the coordination chemistry of functionalized ionic liquids. Smooth layers of cobalt metal could be obtained by electrodeposition of the cobalt-containing ionic liquids.
ISSN: 0947-6539
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
Chemistry - miscellaneous
Biochemistry, Molecular and Structural Biology Section
Department of Materials Engineering - miscellaneous
Chemical and Extractive Metallurgy Section (-)
× corresponding author
# (joint) last author

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