Title: Design of Optimum Zeolite Pore System for Central Hydrocracking of Long-Chain n-Alkanes based on a Single-Event Microkinetic Model
Authors: Thybaut, Joris W ×
Choudhury, Indranil R
Denayer, Joeri F
Baron, Gino V
Jacobs, Pierre
Martens, Johan
Marin, Guy B #
Issue Date: Aug-2009
Publisher: Baltzer Science Publishers
Series Title: Topics in Catalysis vol:52 issue:9 pages:1251-1260
Abstract: Model based catalyst design is an emerging methodology in the development of new catalytic materials with properties tailored to the needs of specific industrial applications. A Single-Event MicroKinetic model (SEMK) was used to assess the hydrocracking behavior of n-dodecane, 4,4,6-trimethyl nonane and 2,5,8-trimethyl nonane, on a non-selective USY zeolite. The differences in cracking pattern exhibited by the various feed molecules provide guidelines for the control of the cracked product distribution through modifications of the zeolite pore structure. The connection of ZSM-22 type channels to the zeolite Y super cage is considered in this work. The percentage of C-6 products obtained by central cracking in the chain can be increased from 25% up to 93% by the design of an appropriate zeolite topology combining USY-like super cages with ZSM-22 like channel segments. This is a promising approach for the development of zeolite catalysts for the selective hydrocracking of Fischer Tropsch waxes into middle distillates.
ISSN: 1022-5528
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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