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Title: Identification of 4,5-didemethyl-4-O-alpha-D-glucopyranosylsimmondsin and pinitol alpha-D-galactosides in jojoba seed meal (Simmondsia chinensis)
Authors: Van Boven, Maurits ×
Leyssen, T
Busson, Roger
Holser, R
Cokelaere, Marnix
Flo, Gerda
Decuypere, Eddy #
Issue Date: Sep-2001
Series Title: Journal of Agricultural and Food Chemistry vol:49 issue:9 pages:4278-83
Abstract: The isolation and identification of two pinitol alpha-D-galactosides from jojoba meal are described. The products were isolated by a combination of preparative HPLC on silica gel and TLC on amino silica gel and were identified by MS, NMR spectroscopy, and chemical derivatization as 5-O-(alpha-D-galactopyranosyl)-3-O-methyl-D-chiro-inositol or 5-alpha-D-galactopyranosyl-D-pinitol and 2-O-(alpha-D-galactopyranosyl)-3-O-methyl-D-chiro-inositol or 2-alpha-D-galactopyranosyl-D-pinitol. The same preparative HPLC method on silica gel allowed a new simmondsin derivative to be isolated and identified as 4,5-didemethyl-4-O-alpha-D-glucopyranosylsimmondsin mainly by NMR spectroscopy and high-resolution mass spectrometry.
URI: 
ISSN: 0021-8561
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Toxicology and Pharmacology
Interdisciplinary Research Facility Life Sciences, Campus Kulak Kortrijk
Faculty of Medicine, Campus Kulak Kortrijk
Division of Livestock-Nutrition-Quality (-)
Medicinal Chemistry (Rega Institute)
× corresponding author
# (joint) last author

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