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Title: Shape selective adsorption of linear and branched alkanes in the Cu3(BTC)2 metal-organic framework
Authors: Finsy, Vincent
De Bruyne, Selm
Alaerts, Luc
De Vos, Dirk
Jacobs, Pierre
Baron, Gino
Denayer, Joeri
Issue Date: 2007
Publisher: Elsevier
Host Document: Studies in Surface Science and Catalysis - From Zeolites to Porous MOF Materials edition:170 pages:2048-2053
Conference: International Zeolite Conference edition:15 location:Beijing, China date:12-17 August 2007
Abstract: Low coverage adsorption properties of C2-C7 linear and C5-C7 iso-alkanes are measured. Shape selective properties of the Cu3(BTC)2 MOF are determined using the pulse chromatographic technique. Preferential adsorption of linear over methylbranched alkanes is observed. Linear alkanes fit better in the pores resulting in stronger interaction with the framework atoms, and thus longer retention.
Publication status: published
KU Leuven publication type: IHb
Appears in Collections:Centre for Surface Chemistry and Catalysis

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