Title: MCM-41 immobilised borate co-catalyst for metallocene catalyzed propene oligomerisation
Authors: Kwanten, Marc ×
Carriere, BAM
Grobet, Pierre
Jacobs, Pierre #
Issue Date: 2003
Series Title: Chemical communications issue:13 pages:1508-1509
Abstract: Reaction of tris( pentafluorophenyl) boron with the silanol groups of MCM-41 resulted in the heterogeneous tris( pentafluorophenyl) borate anion. This immobilised weakly-coordinating anion retains metallocenes, thus yielding a heterogeneous propene oligomerisation catalyst. Activity comparable to the corresponding homogeneous catalyst can be obtained. The products typically consist of over 90% 1-alkenes with Flory-Schulz carbon number distribution.
ISSN: 1359-7345
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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