Title: Impregnation of dimeric Cr-III(salen) on silica and its application in epoxide asymmetric ring opening reactions
Authors: Dioos, BML ×
Jacobs, Pierre #
Issue Date: Mar-2005
Series Title: Applied catalysis. A: General vol:282 issue:1-2 pages:181-188
Conference: date:Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium
Abstract: The heterogeneous asymmetric ring opening (ARO) of epoxides with trimethylsilylazide (TMSN3) catalysed by a dimeric Cr(salen) catalyst impregnated on a silica material combines high enantioselectivities for epoxide and ring opened product with good conversions and suffers only from low leaching in both batch and continuous flow experiments. (c) 2004 Elsevier B.V. All rights reserved.
ISSN: 0926-860X
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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