ITEM METADATA RECORD
Title: FACTORS INFLUENCING THE CATALYTIC ACTIVITY OF TITANIUM SILICALITES IN SELECTIVE OXIDATIONS
Authors: HUYBRECHTS, DRC ×
VAESEN, I
LI, HX
Jacobs, Pierre #
Issue Date: 1991
Publisher: BALTZER SCI PUBL BV
Series Title: Catalysis Letters vol:8 issue:2-4 pages:237-244
Abstract: Titanium silicalites synthesized via different procedures are tested in the oxidation of phenol, 1-octene and n-hexane by aqueous H2O2. It is shown that the presence of titanyl groups, on which H2O2 is activated by formation of titanium peroxo complexes, is a prerequisite for oxygenation activity. Furthermore, in order to afford high selectivities, titanium silicalities should be free of impurities which cause acid catalyzed side reactions or H2O2 decomposition.
ISSN: 1011-372X
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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