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Title: Hydroxylation of Phenol with Hydrogen-Peroxide on Eurots-1 Catalyst
Authors: Martens, Johan ×
Buskens, P
Jacobs, Pierre
Vanderpol, A
Vanhooff, JHC
Ferrini, C
Kouwenhoven, HW
Kooyman, PJ
Vanbekkum, H #
Issue Date: 1993
Publisher: ELSEVIER SCIENCE BV
Series Title: Applied catalysis. A: General vol:99 issue:1 pages:71-84
Conference: date:TECH UNIV EINDHOVEN,VAKGRP TAK,5600 MB EINDHOVEN,NETHERLANDS; SWISS FED INST TECHNOL,TECH CHEM LAB,CH-8092 ZURICH,SWITZERLAND; TECH UNIV DELFT,ORGAN CHEM KATALYSE LAB,2628 BL DELFT,NETHERLANDS
Abstract: The catalytic performance of a standard titanium molecular sieve catalyst, EUROTS-1, has been evaluated at four European universities. The hydroxylation of phenol into catechol and hydroquinone with aqueous H2O2 solution was selected as catalytic test reaction. The use of standard EUROTS-1 catalyst permitted to establish a reproducible standard reaction procedure. The calcination conditions of the catalyst, the use of internal standards, and the nature and the amount of the solvent added to the reaction mixture were found to be major factors determining phenol conversion, product selectivity and hydrogen peroxide product yield.
ISSN: 0926-860X
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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