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Title: SELECTIVE SYNTHESIS OF OXIMES WITH PRIMARY ALIPHATIC-AMINES AND HYDROGEN-PEROXIDE IN THE PRESENCE OF CATALYTIC QUANTITIES OF TITANIUM SILICALITE MOLECULAR-SIEVES
Authors: REDDY, JS ×
Jacobs, Pierre #
Issue Date: 1993
Publisher: ROYAL SOC CHEMISTRY
Series Title: Journal of the Chemical Society. Perkin transactions 1 issue:22 pages:2665-2666
Abstract: Primary aliphatic amines with alpha-hydrogen atoms are oxidized in the presence of hydrogen peroxide as oxidant and catalytic quantities of titanium silicalite molecular sieves to give the corresponding oximes as the main products; the latter are formed with good substrate selectivity and peroxide efficiency. Since the substrate dimensions allow an intracrystalline reaction, by-products, which become significant for larger substrates, are determined by steric constraints in the intracrystalline voids rather than by reaction of electrophilic oxygen with carbon of increased nucleophilicity.
ISSN: 0300-922X
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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