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Title: Catalytic tuning of the olefin epoxidation with hydrogen peroxide and Faujasite Y occluded Mn bipyridine complexes
Authors: Knops-Gerrits, PP ×
Toufar, H
Jacobs, Pierre #
Issue Date: 1997
Publisher: ELSEVIER SCIENCE PUBL B V
Series Title: Studies in surface science and catalysis vol:105 issue:Part A-C pages:1109-1116
Abstract: A series of cation (e.g. Li, Na, K) exchanged [Mn(Bpy)(2)](2+)-Y catalysts was prepared and tested in alkene oxidation reactions with hydrogen peroxide. The activity and selectivity undergoes marked influence from pre-ion exchange. Higher epoxide yields could be obtained for Li-pre-exchanged [Mn(Bpy)(2)](2+)-LiY. The Li+ cation promotes hydrogen peroxide activation at the active site, resulting in a higher cyclohexene epoxidation rate.
Description: PROGRESS IN ZEOLITE AND MICROPOROUS MATERIALS, PTS A-C
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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