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Title: Selective epoxidation of monoterpenes with methyltrioxorhenium and H2O2
Authors: Villa, AL ×
De Vos, Dirk
Montes de Correa, C
Jacobs, Pierre #
Issue Date: 1998
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Series Title: Tetrahedron letters vol:39 issue:46 pages:8521-8524
Conference: date:Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, B-3001 Heverlee, Belgium; Univ Antioquia, Dept Ingn Quim, Medellin, Colombia
Abstract: In the presence of pyridine as a co-catalyst, CH3ReO3 catalyses the epoxidation of terpenes such as alpha-pinene with H2O2 with minimal rearrangement of the epoxide. Pyridine is also critical to suppress isomerisation of the olefin substrate (in case of nerol, geraniol). The reaction can be directed towards selective single or double epoxidation, or in one step towards the rearranged product (e.g. from linalool to the ring-closure product linalool oxide). (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
ISSN: 0040-4039
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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