Title: Oligomerization of propene on an alumoxane-grafted MCM-41 host with bis(cyclopentadienyl)zirconium dimethyl (Cp2Zr(CH3)(2))
Authors: Van Looveren, L ×
De Vos, Dirk
Vercruysse, K
Geysen, DF
Janssen, B
Jacobs, Pierre #
Issue Date: 1998
Series Title: Catalysis Letters vol:56 issue:1 pages:53-56
Conference: date:Katholieke Univ Leuven, Fac Agr & Appl Biol Sci, Ctr Surface Sci & Catalysis, B-3001 Heverlee, Belgium
Abstract: The anchoring of alumoxane, synthesized by the in situ hydrolysis of trimethylaluminum, on the internal pore walls of a mesoporous MCM-41 support generates a highly active and selective host for bis(cyclopentadienyl)zirconium dimethyl (Cp2Zr(CH3)(2)) in the oligomerization of propane. The regioselective preference of the immobilized metallocene is preserved and a typical Flory-Schulz distribution for the propene oligomers is obtained.
ISSN: 1011-372X
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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