Title: Asymmetric hydroformylation of vinyl acetate with BINAP-rhodium(I) complexes
Authors: Hoegaerts, Dirk ×
Jacobs, Pierre #
Issue Date: 1999
Series Title: Tetrahedron: asymmetry vol:10 issue:15 pages:3039-3043
Conference: date:Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, B-3001 Heverlee, Belgium
Abstract: Complexes of (R)-BINAP (BINAP=2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) derived from the available rhodium precursors Rh(acac)(CO)(2) and [Rh(mu-OMe)(cod)](2) are used for the asymmetric hydroformylation of vinyl acetate. Enantiomeric excesses of up to 60% are achieved with regioselectivities of up to 99%. Only a BINAP/Rh ratio of 2 is required. Effects of pressure and temperature on catalyst stability, enantio- and chemoselectivity are discussed. (C) 1999 Elsevier Science Ltd. All rights reserved.
ISSN: 0957-4166
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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