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Title: Low metal loading Ru-MCM-41 stereocontrolled hydrogenation of prostaglandin intermediates
Authors: Coman, S ×
Florea, M
Cocu, F
Parvulescu, VI
Jacobs, Pierre
Danumah, C
Kaliaguine, S #
Issue Date: 1999
Publisher: ROYAL SOC CHEMISTRY
Series Title: Chemical communications issue:21 pages:2175-2176
Conference: date:Univ Bucharest, Dept Chem Technol & Catalysis, Bucharest 70346, Romania; Katholieke Univ Leuven, Dept Interphase Chem, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium; Univ Laval, Dept Genie Chim, St Foy, PQ G1K 7P4, Canada
Abstract: Low metal loading Ru-MCM-41 (0.134 and 0.667 wt% Ru) have been prepared by adsorption of ruthenocene from a diethyl ether solution, calcination and reduction under flowing hydrogen at 350 degrees C; the physical characteristion by a combination of several techniques has shown that Ru is homogeneously distributed inside the MCM pores, and that it is only partially reduced; these catalysts exhibit a very high diastereoselectivity in hydrogenation of an F prostaglandin intermediate leading only to the 11S,15R diastereomer.
ISSN: 1359-7345
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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