Title: On the triplet-singlet energy gap of acetylene
Authors: Le, HT ×
Flock, M
Nguyen, Minh Tho #
Issue Date: 2000
Series Title: Journal of Chemical Physics vol:112 issue:16 pages:7008-7010
Conference: date:HoChiMinh City Univ Technol, Fac Chem Engn, Ho ChiMinh City, Vietnam; Univ Leuven, Dept Chem, B-3001 Louvain, Belgium
Abstract: The triplet-singlet energy gap of acetylene, T-e(B-3(2)-(1)Sigma(g)(+)), was calculated using the coupler-cluster theory including all single and double excitations plus perturbative corrections for the triples, and multiconfigurational second-order perturbation theory methods with large basis sets. The cis-bent triplet state ((a) over tilde B-3(2)) is calculated to lie 30 500 +/- 500 cm(-1) above the ground singlet state ((1)Sigma(g)(+)); the latter value differs somewhat from the most recent evaluation of T-0=28 900 cm(-1) [Amed , J. Chem. Phys. 110, 4248 (1999)] but agrees well with an earlier theoretical estimate of 30 270 cm(-1) [Yamaguchi , Theor. Chim. Acta 86, 97 (1993)]. Thus the discrepancy of 1000 cm(-1) may well arise from an interpretation of experimental results rather than a shortcoming of theoretical calculations. (C) 2000 American Institute of Physics. [S0021-9606(00)30616-X].
ISSN: 0021-9606
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Quantum Chemistry and Physical Chemistry Section
× corresponding author
# (joint) last author

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