Title: Evidence for the production of propene ion in the gas phase. Reaction of ionized dichlorocarbene with acetone
Authors: Flammang, R ×
Van Haverbeke, Y
Gerbaux, P
Nguyen, Minh Tho #
Issue Date: 2001
Series Title: Tetrahedron letters vol:42 issue:4 pages:669-671
Conference: date:Univ Mons, Organ Chem Lab, B-7000 Mons, Belgium; Univ Louvain, Dept Chem, B-3001 Heverlee, Belgium
Abstract: Experimental evidence for the production of propene ion in the gas phase reaction of ionized dichlorocarbene with acetone is provided owing to the use of an original hybrid tandem mass spectrometer of sector-quadrupole sector configuration. Ionized dimethylcarbene is a transient intermediate that rapidly rearranges into its more stable isomer. Relative stabilities between both isomeric forms in different electronic states are evaluated using B3LYP/6-311++G(d,p) computations. (C) 2001 Elsevier Science Ltd. All rights reserved.
ISSN: 0040-4039
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Quantum Chemistry and Physical Chemistry Section
× corresponding author
# (joint) last author

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