Advanced Functional Materials

Publication date: 2010-01
Volume: 20 Pages: 983 - 991
ISSN: 1616-301X, 1616-3028
DOI: 10.1002/adfm.200901732
Publisher: Wiley-VCH Verlag GmbH


Pellicer, Eva
Varea, Aïda ; Pané, Salvador ; Nelson, Bradley J ; Menéndez Dalmau, Enric ; Estrader, Marta ; Suriñach, Santiago ; Baró, Maria Dolors ; Nogués, Josep ; Sort, Jordi


03 Chemical Sciences, 09 Engineering, 02 Physical Sciences, Materials


Nanocrystalline 3mm thick Cu1–xNix (0.45 ≤ x ≤ 0.87) films are electrodeposited galvanostatically onto Cu/Ti/Si (100) substrates, from a citrate- and sulphate-based bath containing sodium lauryl sulphate and saccharine as additives. The films exhibit large values of reduced Young’s modulus (173 < / Er < / 192 GPa) and hardness (6.4 < /H < / 8.2 GPa), both of which can be tailored by varying the alloy composition. The outstanding mechanical properties of these metallic films can be ascribed to their nanocrystalline nature—as evidenced by X-ray diffraction, transmission electron microscopy, and atomic force microscopy—along with the occurrence of stacking faults and the concomitant formation of intragranular nanotwins during film growth. Due to their nanocrystalline character, these films also show very low surface roughness (root mean square deviation of around 2 nm). Furthermore, tunable magnetic properties, including a transition from paramagnetic to ferromagnetic behavior, are observed when the Ni percentage is increased. This combination of properties, together with the simplicity of the fabrication method, makes this system attractive for widespread technological applications, including hard metallic coatings or magnetic micro/nano-electromechanical devices.