Download PDF

Journal of Materials Chemistry

Publication date: 2010-01-01
Volume: 20 Pages: 8571 - 8574
Publisher: Royal Society of Chemistry

Author:

Cardinaels, Thomas
Hirai, Yuki ; Hanabusa, Kenji ; Binnemans, Koen ; Kato, Takashi

Keywords:

self-assembled fibers, electrooptical properties, prominent gelation, liquid crystals, soft materials, photoluminescence, lanthanidomesogens, organogels, luminescence, gelators, lanthanides, rare earths, europium, metallomesogens, Science & Technology, Physical Sciences, Technology, Chemistry, Physical, Materials Science, Multidisciplinary, Chemistry, Materials Science, SELF-ASSEMBLED FIBERS, ELECTROOPTICAL PROPERTIES, PROMINENT GELATION, ORGANIC FLUIDS, SOFT MATERIALS, PHOTOLUMINESCENCE, AGGREGATION, ORGANOGELS, LUMINESCENCE, GELATORS, 03 Chemical Sciences, 09 Engineering, Nanoscience & Nanotechnology

Abstract:

A red-emitting molecular europium(III) complex has been doped into liquid-crystalline (LC) physical gels consisting of 4-pentyl-4'-cyanobiphenyl (5CB) with amino acid-based gelators. Light scattering cells on the basis of these LC physical gels could be switched between a non-transparent off-state and a transparent on-state by on-off application of electric fields. The gels produced intense red light when they were irradiated with UV-light.